Applying 3D Geostatistical Simulation to Improve the Groundwater Management Modelling of Sedimentary Aquifers: The Case of Doñana (Southwest Spain)

Mathematical groundwater modelling with homogeneous permeability zones has been used for decades to manage water resources in the Almonte-Marismas aquifer (southwest Spain). This is a highly heterogeneous detrital aquifer which supports valuable ecological systems in the Doñana National Park. The present study demonstrates that it is possible to better characterize this heterogeneity by numerical discretization of the geophysical and lithological data available. We identified six hydrofacies whose spatial characteristics were quantified with indicator variogram modelling. Sequential Indicator Simulation then made it possible to construct a 3D geological model. Finally, this detailed model was included in MODFLOW through the Model Muse interface. This final process is still a challenge due to the difficulty of downscaling to a handy numerical modelling scale. New piezometric surfaces and water budgets were obtained. The classical model with zones and the model with 3D simulation were compared to confirm that, for management purposes, the effort of improving the geological heterogeneities is worthwhile. This paper also highlights the relevance of including subsurface heterogeneities within a real groundwater management model in the present global change scenario

Clustering Groundwater Level Time Series of the Exploited Almonte-Marismas Aquifer in Southwest Spain

Groundwater resources are regularly the principal water supply in semiarid and arid climate areas. However, groundwater levels (GWL) in semiarid aquifers are suffering a general decrease because of anthropic exploitation of aquifers and the repercussions of climate change. Effective groundwater management strategies require a deep characterization of GWL fluctuations, in order to identify individual behaviors and triggering factors. In September 2019, the Guadalquivir River Basin Authority (CHG) declared that there was over-exploitation in three of the five groundwater bodies of the Almonte-Marismas aquifer, Southwest Spain. For that reason, it is critical to understand GWL dynamics in this aquifer before the new Spanish Water Resources Management Plans (2021–2027) are developed. The application of GWL series clustering in hydrogeology has grown over the past few years, as it is an extraordinary tool that promptly provides a GWL classification; each group can be related to different responses of a complex aquifer under any external change. In this work, GWL time series from 160 piezometers were analyzed for the period 1975 to 2016 and, after data pre-processing, 24 piezometers were selected for clustering with k-means (static) and time series (dynamic) clustering techniques. Six and seven groups (k) were chosen to apply k-means. Six characterized types of hydrodynamic behaviors were obtained with time series clustering (TSC). Number of clusters were related to diverse affections of water exploitation depending on soil uses and hydrogeological spatial distribution parameters. TSC enabled us to distinguish local areas with high hydrodynamic disturbance and to highlight a quantitative drop of GWL during the studied period

Modelos estadísticos de predicción ARIMA de precipitaciones en dos estaciones españolas representativas de dos grupos con diferentes características climáticas

Ponencia presentada en: VI Congreso Internacional de la Asociación Española de Climatología celebrado en Tarragona del 8 al 11 de octubre de 2008.[ES]Las series de datos pluviométricas, además de otras variables climáticas (temperaturas, insolación, etc.), desempeñan un papel muy importante en la caracterización del clima. Para su análisis con el fin de obtener modelos de predicción, las series de datos y, en este caso concreto, de precipitaciones mensuales deben haber sido observadas por un periodo de, al menos 20 a 30 años, lo que se llama un período largo de observación.[EN]Pluviometric data series and other climate variables (temperatures, hours of sunshine,…) play a very important role in the characterization of climate. To analyse them with the aim to obtain forecast models, the data series and, in this case, monthly rainfall data, must have been measured during a long time period, at least 20 or 30 years (long record of data)

A survey of domestic wells and pit latrines in rural settlements of Mali: Implications of on-site sanitation on the quality of water supplies

On-site sanitation is generally advocated as a means to eradicate the health hazards associated with open defecation. While this has provided a welcome upgrade to the livelihoods of millions of people in low-income countries, improved sanitation facilities are increasingly becoming a threat to domestic groundwater-based supplies. Within this context, a survey of pit latrines, domestic wells and improved water sources was carried out in a large rural village of southern Mali. All households were surveyed for water, sanitation and hygiene habits. Domestic wells and improved water sources were georeferenced and sampled for water quality (pH, electric conductivity, temperature, turbidity, total dissolved solids, thermotolerant coliforms, chloride and nitrate) and groundwater level, while all latrines were inspected and georeferenced. A GIS database was then used to evaluate the proportion of water points within the influence area of latrines, as well as to underpin multiple regression models to establish the determinants for fecal contamination in drinking supplies. Moreover, an appraisal of domestic water treatment practices was carried out. This revealed that nearly two-thirds of the population uses bleach to purify drinking supplies, but also that domestic-scale treatment as currently implemented by the population is far from effective. It is thus concluded that existing habits could be enhanced as a means to make water supplies safer. Furthermore, population, well and latrine density were all identified as statistically significant predictors for fecal pollution at different spatial scales. These findings are policy-relevant in the context of groundwater-dependent human settlements, since many countries in the developing world currently pursue the objective of eliminating open defecation

Los juegos del agua: el desafío de la gestión de las aguas subterráneas

El juego tiene una duración aproximada de 2,5 horas y ayuda a despertar el interés del alumnado sobre los retos del uso y gestión de las aguas subterráneas, haciéndoles por tanto receptivos a los contenidos teóricos relacionados que se explican en las clases siguientes (medidas de gestión del agua, normativa, etc.)

Physical and chemical characterization of building materials

The products used in the construction of buildings and infrastructures, are made from raw material extracted directly from nature, and after suitable transformation processes are placed on site. Approximately 2.5 tons of materials per square meter are used in a residential building. The most abundant percentages are: Gravel and sand 57.8, ceramics 21.6, cement 12.5, lime 1.98 and gypsum 0.46. Some materials used cause a high impact of negative character in the environment but their quantification is low whereas others of low impact but are used of massive form in construction reason why they can cause serious hazards for the human health. The raw material used in the manufacture of construction materials is extracted directly from nature or is originated by a mixture of raw material and recycled material. In any case, it is necessary to analyze the chemical composition of the construction products whether they are natural, whether they are transformed or mixed. The purpose of this work was to perform a physical-chemical characterization of samples from factories located in three regions of different geological nature: granitic, calcareous and sedimentary. The materials analyzed come from different factories located in Spain 18 factories of cements, bricks and tiles 15, ceramics 16, sands 15 and natural stones 18. They were supplied by manufacturers and it has been made a physic-chemical characterization of the samples received. The chemical composition of the samples of cement, brick, ceramic and roofing tile has been made using ICP-MS and EDXRF. The results of these analyze shows near 72 different elements. The higher concentrations are of Na, K, Ca, Al, Fe and Si. All the samples were also characterized using XRPD. It is a powerful tool for material characterization in general, and cements materials in particular. The use of the Rietveld method has allowed quantifying the clinkers and cements measured by laboratory x-ray powder diffraction (LXRPD) giving their accurate phase assemblage. From the average composition of the different classes of cements analyzed, it is concluded that, except for two samples, the rest all correspond to Portland cements of different strength.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Multiclass spatial predictions of borehole yield in southern Mali by means of machine learning classifiers

Study region: Regions of Bamako, Kati and Kangaba, southwestern Mali Study focus: Machine learning-based mapping of borehole yield. Three algorithms were trained on an imbalanced multiclass database of boreholes, while twenty variables were used as predictors for borehole yield. All models returned balanced and geometric scores in the order of 0.80, with area under the receiver operating characteristic curve up to 0.87. Three main methodological conclusions are drawn: (a) The evaluation of different machine learning classifiers and various resampling strategies and the subsequent selection of the best performing ones is shown to be a good strategy in this type of studies; (b) ad hoc calibration tools, such as data on borehole success rates, provide an apt complement to standard machine learning metrics; and (c) a multiclass approach with an unbalanced database represents a greater challenge than predicting a bivariate outcome, but potentially results in a finer depiction of field conditions. New hydrological insights for the region: Alluvial sediments were found to be the most productive areas, while the Mandingue Plateau has the lowest groundwater potential. The piedmont areas showcase an intermediate groundwater prospect. Elevation, basement depth, slope and geology rank among the most important variables. Lower values of clay content, slopes and elevations, and higher values of basement depth and saturated thickness were linked to the most productive class

Analysis of the information about Doctoral Degrees presented in the Spanish universities websites.

Globalization has intensified competition, as evidenced by the growing number of international classification systems (rankings) and the attention paid to them. Doctoral education has an international character in itself. It should promote opportunities for graduate students lo participate in these international studies. The quality and competitiveness are two of the most important issues for universities. To promote the interest of graduates to continue their education after the graduate level, it would be necessary to improve the published information of ihe doctoral programs. It should increase the visibility and provide high-quality, easily accessible and comparable information which includes all the relevant aspects of these programs. The authors analysed the website contents of doctoral programs, it was observed a lack of quality of them and very poor information about the contents, so that it was decided that any of them could constitute a model for creating new websites. The recommendations on the format and contents in the web were made by a discussion group. They recommended an attractive design; a page with easy access to contents and easy to find on Ihe net and with the information in more than one language. It should include complete program and academic staff information. It should also be included the study's results which should be easily accessible and includes quantitative data, such as number of students who completed scholars, publications, research projects, average duration of the studies, etc. It will facilitate the choice of progra

Naica's "Cueva de los Cristales": Synchrotron radiation characterization of the wall-crystal interface

Naica's "Cueva de los Cristales" was discovered in 2000. It has been considered particularly interesting for its beauty and the challenges it poses to crystallography. This article focuses on the study of the wall-selenite interface by various techniques, particularly X-ray diffraction (XRD), scanning electron microscopy (SEM), with emphasis on micro-X-ray fluorescence (micro-XRF) and micro-X-ray absorption near edge structure (micro-XANES). The main phases calcite, quartz, goethite and montmorillonite were identified by XRD, as well as the association of crystalline and amorphous minor and trace phases of Zn, Mn, Cu, As and Pb. The latter were identified in micro-XRF maps and micro-XANES spectra. The results for the morphology and the chemical description of the crystal-wall interface may contribute to propose a nucleation and growth mechanism for Naica megacrystals

Oral fosfomycin for the treatment of lower urinary tract infections among kidney transplant recipients—Results of a Spanish multicenter cohort

Preliminary results of this study were presented at the 29th European Congress of Clinical Microbiology and Infectious Diseases (ECCMID), held in Amsterdam, The Netherlands, from 13 to 16 April, 2019 (oral communication O‐0699).Oral fosfomycin may constitute an alternative for the treatment of lower urinary tract infections (UTIs) in kidney transplant recipients (KTRs), particularly in view of recent safety concerns with fluroquinolones. Specific data on the efficacy and safety of fosfomycin in KTR are scarce. We performed a retrospective study in 14 Spanish hospitals including KTRs treated with oral fosfomycin (calcium and trometamol salts) for posttransplant cystitis between January 2005 and December 2017. A total of 133 KTRs developed 143 episodes of cystitis. Most episodes (131 [91.6%]) were produced by gram‐negative bacilli (GNB), and 78 (54.5%) were categorized as multidrug resistant (including extended‐spectrum β‐lactamase‐producing Enterobacteriaceae [14%] or carbapenem‐resistant GNB [3.5%]). A median daily dose of 1.5 g of fosfomycin (interquartile range [IQR]: 1.5‐2) was administered for a median of 7 days (IQR: 3‐10). Clinical cure (remission of UTI‐attributable symptoms at the end of therapy) was achieved in 83.9% (120/143) episodes. Among those episodes with follow‐up urine culture, microbiological cure at month 1 was achieved in 70.2% (59/84) episodes. Percutaneous nephrostomy was associated with a lower probability of clinical cure (adjusted odds ratio: 10.50; 95% confidence interval: 0.98‐112.29; P = 0.052). In conclusion, fosfomycin is an effective orally available alternative for treating cystitis among KTRs.This study was supported by Plan Nacional de I+D+i 2013‐2016 and Instituto de Salud Carlos III, Subdirección General de Redes y Centros de Investigación Cooperativa, Ministerio de Ciencia, Innovación y Universidades, Spanish Network for Research in Infectious Diseases (REIPI RD16/0016)—cofinanced by the European Development Regional Fund “A way to achieve Europe”; the Group for Study of Infection in Transplantation and the Immunocompromised Host (GESITRA‐IC) of the Spanish Society of Clinical Microbiology and Infectious Diseases (SEIMC); and the Spanish Network for Research in Renal Diseases (REDInREN RD16/0009). MFR holds a research contract “Miguel Servet” (CP 18/00073) from the Spanish Ministry of Science, Innovation and Universities, Instituto de Salud Carlos III